ex-wife

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ex-wife [noun]

Someone's ex-wife is the woman they were once married to.

US /ˌeksˈwaɪf/ 
UK /ˌeksˈwaɪf/ 

Cambridge Advanced Learner's Dictionary

ex- ˈ wife / ˌeksˈwaɪf / noun [ C ]

Someone's ex-wife is the woman they were once married to.

Collins Advanced Learner’s English Dictionary

noun

a former wife

Merriam-Webster's Advanced Learner's Dictionary

a woman to whom one was formerly married a former wife